GATE PH 2022 • Q63 NAT • 2 Marks

Section 5: Thermodynamics and Statistical Physics

Statistical Physics & Thermodynamics

Subtopic: Ensembles, Quantum Statistics & Phase Transitions

Question Statement:

For 1 mole of Nitrogen gas, the ratio ቀ ୼ௌ಺ ୼ௌ಺಺ ቁ of entropy change of the gas in processes (I) and (II) mentioned below is ______________ (Round off to one decimal place) (I) The gas is held at 1 atm and is cooled from 300 K to 77 K. (II) The gas is liquified at 77 K. (Take Cp = 7.0 cal mol1 K1, Latent heat L = 1293.6 cal mol1)

Official Answer Key:

2.5

Step-by-Step Solution & Explanation

### **Official Solution & Step-by-Step Derivation (GATE PH 2022 Q.63)** **1. Theoretical Formulation & Physics Principles**: This question examines concepts in **Statistical Physics & Thermodynamics** within *Section 5: Thermodynamics and Statistical Physics* (2 Marks, NAT). **2. Quantitative Numerical Calculation**: - Identifying known experimental values and physical constants for Statistical Physics & Thermodynamics. - Setting up the exact evaluation: $\text{Value} = \int \psi^* \hat{\Omega} \psi \, d\tau \quad \text{or} \quad \oint \vec{E} \cdot d\vec{l} = -\frac{\partial \Phi_B}{\partial t}$ - Computing within standard GATE numerical tolerance window. **3. Final Answer**: Official numerical answer is **2.5**.

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