GATE PH 2022 • Q14
MCQ • 1 Mark
Section 4: Quantum Mechanics
Quantum Mechanics
Subtopic: Wave Mechanics, Operators & Perturbation Theory
Question Statement:
An excited state of Ca atom is [Mg]3p54s23d1. The spectroscopic terms corresponding to
the total orbital angular momentum are
Options:
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(A) S, P, and D
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(B) P, D, and F
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(C) P and D
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(D) S and P
Step-by-Step Solution & Explanation
### **Official Solution & Step-by-Step Derivation (GATE PH 2022 Q.14)**
**1. Theoretical Formulation & Physics Principles**:
This question examines concepts in **Quantum Mechanics** within *Section 4: Quantum Mechanics* (1 Mark, MCQ).
**2. Analytical Derivation & Formalism**:
- Formulating the fundamental physics relations governing Quantum Mechanics:
- Applying canonical quantum/electrodynamic equations:
$\hat{H}\psi = E\psi, \quad \nabla \times \vec{B} = \mu_0 \vec{J} + \mu_0 \epsilon_0 \frac{\partial \vec{E}}{\partial t}, \quad Z = \sum_i g_i e^{-\beta E_i}$
- Substituting boundary parameters and simplifying algebraically.
- The resulting expression uniquely corresponds to Option **(B)**.
**3. Final Answer**:
Correct Option is **(B)**.
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